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Because of its connection with laser technology, the theory of infrared and Raman vibrational spectra is even more important now than when this book was first published. As the pioneering text in the field and as the text still preferred today, Molecular Vibrations is the undeniable choice of anyone teaching or studying molecular spectroscopy at the graduate level. It is the only book of its kind in the area written by well-known scientists, and besides its value as a pedagogical classic, it is an essential reference for anyone engaged in research.
The genius of the book is its rigorous, elegant treatment of the mathematics involved in detailed vibrational analyses of polyatomic molecules. The reader is led carefully and gradually through the main features of the theory and its methods: starting from a valuable introduction to the theory of molecular vibrations and the application of wave mechanics to this subject; leading into the mathematical methods devised by Professor Wilson and his students for handling the mathematical problems and for making use of symmetry and group theory; proceeding through vibrational selection rules and intensities, potential functions and methods of solving the secular determinant; and concluding with a sample vibrational analysis of the molecule of benzene. Sixteen appendices, comprising nearly one hundred pages, offer much extremely useful information that is more clearly understood outside the body of the text.
Well-known for their distinguished contributions to the field, the authors — in addition to Professor Wilson of Harvard University — are J. C. Decius of Oregon State University and Paul C. Cross, late President of Mellon Institute. Younger students interested in the field of molecular spectroscopy will especially welcome this inexpensive reprint edition of an exceptional book.
"An authoritative and complete presentation written on a very high level." — G. Herzberg, Science
"The easiest and quickest route to acquiring skill in handling the mathematics of molecular vibrations." — Nature
- Sales Rank: #1017105 in eBooks
- Published on: 2012-05-11
- Released on: 2012-05-11
- Format: Kindle eBook
Most helpful customer reviews
11 of 11 people found the following review helpful.
very good...
By A Customer
In this one, Wilson writes definitively, math/scientifically, and with sincerity of purpose. Don't get confused by the word 'theory.' There's as much math in here as Born and Wolf's P of O. The only diffenrence is Wilson's is much more algebra-based. The mathematics (i.e. isomorphs) is 'taught', without breaking the flow, and is not assumed that you know the stuff already--- or can find it somewhere else. This book stands out because there is more science in here than names of scientists, and his references are for real. I would also say it was unique because books with titles like 'Molecular Vibrations' are usually skipped over for titles like 'mechanics' or 'quantum theory.' Spectroscopy was a major advancement in science, and it is good to see it skillfully treated with enlightening clarity.
8 of 8 people found the following review helpful.
1955 classic
By A Customer
Reissue of original, which was published in 1955, in the pre-computer age. Solid QM description of vibrating polyatomic molecules, and their interaction with EM radiation. The authors exploit group theory (molecular symmetry) to reduce the calculational work as much as possible. Good introduction to the use of finite groups, e.g. how to exploit the hexagonal symmetry of the benzene molecule.
6 of 6 people found the following review helpful.
A MUST HAVE for those dealing with B matrix methods
By Richard Axor
This is the original work by E.B.Wilson where the G and F matrix formalism is presented. The G matrix, related to kinetic vibrational energy is built uppon the elements of the B matrix defined from "internal coordinates". Many quantum chemistry software packages use this exact methodology to build normal coordinates. For those working on Quantum Chem Molecular Orbital calculations, this book is a must.
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